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dc.contributor.authorRivera Capacho, Luisa Fernanda.-
dc.date.accessioned2026-10-18T00:22:58Z-
dc.date.available2024-
dc.date.available2026-10-18T00:22:58Z-
dc.date.issued2024-
dc.identifier.citationRivera Capacho, L. F. (2024). Síntesis de biopelículas de almidón - hidrolato de cúrcuma para detección de hierro y cobre en soluciones acuosas. [Trabajo de Grado Pregrado, Universidad de Pamplona]. Repositorio Hulago Universidad de Pamplona. https://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/11842es_CO
dc.identifier.urihttps://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/11842-
dc.descriptionEn la presente investigación se sintetizaron biopelículas de almidón de yuca impregnadas con hidrolato de cúrcuma. Esta investigación se centró en el desarrollo de un biosensor para la detección de cationes de Fe+3 y Cu+2 en soluciones acuosas. El almidón extraído de residuos de yuca presentó un rendimiento de 14,07 ± 0,70 %, presentando gránulos elipsoidales truncados y una temperatura de descomposición térmica entre 270,17 °C a 343,72 °C. Cada biopelícula (3,8±0,1 g) se elaboró mezclando 4,87 % de almidón, 1,33 % de glicerina, 90,68 % de agua y 3,10 % de hidrolato de cúrcuma. Las biopelículas obtenidas presentaron una distribución homogénea y una estabilidad térmica hasta 262,31 °C. El hidrolato de cúrcuma fue extraído con etanol al 96 %, obteniendo un porcentaje de peso disuelto de 6,27 ± 0,80 %. Su análisis cromatográfico mostró que sus constituyentes mayoritarios son: α-curcumeno, curcumina, α-turmerona y β-sesquifelandreno. Las biopelículas fueron impregnadas con el hidrolato de cúrcuma, en el cual la curcumina actúa como cromóforo formando complejos con los metales y produciendo cambios de color visibles. Para la detección de la concentración por espectroscopía UV-vis, de los iones Fe+3 y Cu+2, se diseñaron láminas de detección de 10 mm x 15 mm con un paso óptico de 12,83 mm x 5,13 mm. El análisis espectrofotométrico se realizó a 455 nm para el hierro y 430 nm para el cobre. Las curvas de calibración (para ambos metales) presentaron un comportamiento exponencial para concentraciones de 0, 3, 5, 7 y 10 ppm de ambos metales. Este biosensor ofrece una alternativa sostenible y económica a los métodos convencionales, aprovechando recursos locales y residuos agrícolas. El método proporciona una detección visual rápida y cuantificación espectrofotométrica, con potencial aplicación en monitoreo ambiental y análisis en campo.es_CO
dc.description.abstractIn this research, cassava starch biofilms impregnated with turmeric hydrolate were synthesized. This research focuses on the development of a biosensor for the detection of Fe+3 and Cu+2 cations in aqueous solutions. The starch extracted from cassava residues had a yield of 14.07 ± 0.70 %, with truncated ellipsoidal granules and a thermal decomposition temperature between 270.17 °C to 343.72 °C. Each biofilm (3.8±0.1 g) was made by mixing 4.87 % starch, 1.33 % glycerin, 90.68% water and 3.10% turmeric hydrolate. The biofilms obtained have a homogeneous distribution and thermal stability up to 262.31 °C. Turmeric hydrolate was extracted with 96 % ethanol, obtaining a dissolved weight percentage of 6.27 ± 0.80 %. Its chromatographic analysis showed that its major constituents are α-curcumene, curcumin, α-turmerone and β-sesquiphellandrene. The biofilms were impregnated with turmeric hydrolate, in which curcumin acts as a chromophore, forming complexes with metals and producing visible color changes, for the detection of the concentration by UV-vis spectroscopy of the Fe+3 and Cu+2 ions, 10 mm x 15 mm detection sheets are designed with an optical path of 12.83 mm x 5.13 mm. Spectrophotometric analysis was performed at 455 nm for iron and 430 nm for copper. The calibration curves (for both metals) showed exponential behavior for concentrations of 0, 3, 5, 7 and 10 ppm of both metals. This biosensor offers a sustainable and economical alternative to conventional methods, taking advantage of local resources and agricultural waste. The method provides rapid visual detection and spectrophotometric quantification, with potential application in environmental monitoring and field analysis.es_CO
dc.format.extent73es_CO
dc.format.mimetypeapplication/pdfes_CO
dc.language.isoeses_CO
dc.publisherUniversidad de Pamplona - Facultad de Ciencias Básicas.es_CO
dc.subjectBiosensor.es_CO
dc.subjectCuantificación.es_CO
dc.subjectHierro.es_CO
dc.subjectCobre.es_CO
dc.subjectAmidón.es_CO
dc.subjectHidrolato de cúrcuma.es_CO
dc.titleSíntesis de biopelículas de almidón - hidrolato de cúrcuma para detección de hierro y cobre en soluciones acuosas.es_CO
dc.typehttp://purl.org/coar/resource_type/c_7a1fes_CO
dc.date.accepted2024-
dc.description.editionUniversidad de Pamplona - Facultad de Ciencias Básicas.es_CO
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