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    dc.contributor.authorVillamizar Cedeño, Carlos Humberto.-
    dc.date.accessioned2022-12-02T14:48:07Z-
    dc.date.available2018-09-18-
    dc.date.available2022-12-02T14:48:07Z-
    dc.date.issued2018-
    dc.identifier.citationVillamizar Cedeño, C. H. (2018). Síntesis de una resina alquídica a partir de aceite de palma mediante poli condensación con mezclas de Anhídridos Ftálico/Maleíco [Trabajo de Grado Pregrado, Universidad de Pamplona] Repositorio Hulago Universidad de Pamplona. http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/5051es_CO
    dc.identifier.urihttp://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/5051-
    dc.descriptionSe realizó la síntesis de tres resinas alquídicas por policondensación con diferentes relaciones de anhídridos ftálico/maleíco (2:1, 1:1 y 1:2) a partir de aceite de palma. Se caracterizó tanto el aceite de palma crudo y las diferentes resinas sintetizadas por medio de diferentes técnicas instrumentales y mecánicas. El aceite de palma crudo se caracterizó por cromatografía de gases con detector de ionización en llama (GC/D) y las resinas por medio de las técnicas instrumentales de FT-IR, DCS, TGA, NMR y las propiedades mecánicas fueron medidas por medio de la Reología. Con este trabajo se encontró una disminución en el tiempo de reacción de 210 min a 80 min en el proceso transesterificación, debido a la adición del anhídrido maleíco. Se comprobó mediante las técnicas de instrumentales los grupos funcionales característicos de una resina alquídica, confirmando la presencia el grupo alquídico. El análisis reológico permitió medir diferentes propiedades mecánicas encontrando una clasificación de la síntesis dentro de los polímeros con características similares a las del polietileno de alta densidad. Teniendo posibles usos en diferentes industrias como la de protección de dispositivos, recubrimientos térmicos, pellets, impermeabilización de terrenos (vertederos, piscinas), entre otras.es_CO
    dc.description.abstractThe synthesis of three alkyd resins was carried out by polycondensation with different ratios of phthalic / maleic anhydrides (2: 1, 1: 1 and 1: 2) from palm oil. Both the crude palm oil and the different resins synthesized were characterized by means of different instrumental and mechanical techniques. Crude palm oil was characterized by gas chromatography with flame ionization detector (GC / D) and the resins by means of the instrumental techniques of FT-IR, DCS, TGA, NMR and mechanical properties were measured by means of the Rheology. With this work we found a decrease in the reaction time from 210 min to 80 min in the transesterification process, due to the addition of maleic anhydride. The functional groups characteristic of an alkyd resin was checked by instrumental techniques, confirming the presence of the alkyd group. The rheological analysis allowed to measure different mechanical properties finding a classification of the synthesis within the polymers with characteristics similar to those of high density polyethylene. Having possible uses in different industries such as protection of devices, thermal coatings, pellets, waterproofing of land (landfills, swimming pools), among others.es_CO
    dc.format.extent118es_CO
    dc.format.mimetypeapplication/pdfes_CO
    dc.language.isoeses_CO
    dc.publisherUniversidad de Pamplona – Facultad de Ingenieras y Arquitectura.es_CO
    dc.subjectEl autor no proporciona la información sobre este ítem.es_CO
    dc.titleSíntesis de una resina alquídica a partir de aceite de palma mediante poli condensación con mezclas de Anhídridos Ftálico/Maleíco.es_CO
    dc.typehttp://purl.org/coar/resource_type/c_7a1fes_CO
    dc.date.accepted2018-06-18-
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    dc.type.coarversionhttp://purl.org/coar/resource_type/c_2df8fbb1es_CO
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