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    dc.contributor.authorRedondo Soto, Andres Eloy.-
    dc.date.accessioned2022-12-14T02:29:07Z-
    dc.date.available2020-09-22-
    dc.date.available2022-12-14T02:29:07Z-
    dc.date.issued2020-
    dc.identifier.citationRedondo Soto, A. E. (2020). Evaluación de Separación de Gases Fluorados (F-GASES) utilizando disolventes eutécticos profundos como absorbentes [Trabajo de Grado Pregrado, Universidad de Pamplona] Repositorio Hulago Universidad de Pamplona. http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/5335es_CO
    dc.identifier.urihttp://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/5335-
    dc.descriptionEl impacto ambiental resultante de la liberación de gases fluorados (F-gases), comúnmente utilizados en refrigeración, está impulsando el desarrollo de tecnologías para recuperarlos y reciclarlos. Los líquidos iónicos fluorados (LIFs) se han investigado como candidatos prometedores para la absorción y separación selectiva de F-gases. En este trabajo, preparamos solventes eutécticos profundos (SEPs) compuestos de LIF y ácidos perfluorados, que permitieron explorar las excelentes propiedades de solubilización de gases de los LIF con altos puntos de fusión en un rango más amplio de líquidos. Se realizó un cribado de SEP preparado a partir de 5 LIF diferentes para la solubilización de 1,1,1,2-tetrafluoroetano (R-134a) a 303,15 K, usando un sistema volumétrico de acero inoxidable. [N4444] [C4F9SO3]: C4F9CO2H y [C2C1Im] [C8F17SO3]: C4F9CO2H se seleccionaron como los sistemas con las mejores capacidades de absorción y se estudiaron tres diferentes relaciones de LIF y ácido perfluorado, para la absorción de difluorometano (R-32), pentafluoroetano (R-125) y R-134a a 303.15 K, 313.15 K y 323.15 K. Todos los SEPs estudiados tienen una selectividad ideal hacia R-134a en mezclas con los otros dos F-gases. Los resultados presentados aquí proporcionan conocimiento del comportamiento de estos nuevos solventes alternativos para la separación de mezclas de F-gases de refrigerantes comerciales, a tres temperaturas diferentes y en una amplia gama de presiones de operación.es_CO
    dc.description.abstractThe environmental impact resulting from the release of fluorinated gases (F-gases), commonly used in refrigeration, is prompting the development of technologies to recover and recycle them. Fluorinated Ionic Liquids (FILs) have been investigated as promising candidates for the absorption and selective separation of F-gases. In this work, we prepared Deep Eutectic Solvents (DES) composed of FILs and perfluorinated acids, which allowed to explore the excellent gas solubilization properties of FILs with high melting points in a wider liquidous range. A screening of DES prepared from 5 different FILs was performed for the solubilization of 1,1,1,2- tetrafluoroethane (R-134a) at 303.15 K, using a stainless steel volumetric system. [N4444][C4F9SO3]:C4F9CO2H and [C2C1Im][C8F17SO3]:C4F9CO2H were selected as the systems with the best absorption capacities and were studied in three different FIL:perfluorinated acid ratios, for the absorption of difluoromethane (R-32), pentafluoroethane (R-125), and R-134a at 303.15 K, 313.15 K, and 323.15 K. All studied DES have ideal selectivity towards R-134a in mixtures with the other two F-gases. The results presented here provide knowledge of the behavior of these new alternative solvents for the separation of F-gases mixtures of commercial refrigerants, at three different temperatures and in a wide range of operating pressures.es_CO
    dc.format.extent130es_CO
    dc.format.mimetypeapplication/pdfes_CO
    dc.language.isoeses_CO
    dc.publisherUniversidad de Pamplona – Facultad de Ingenieras y Arquitectura.es_CO
    dc.subjectEfecto invernadero.es_CO
    dc.subjectEquilibrio vapor-liquido.es_CO
    dc.subjectLíquidos iónicos.es_CO
    dc.subjectSelectividad.es_CO
    dc.subjectSolubilidad.es_CO
    dc.titleEvaluación de Separación de Gases Fluorados (F-GASES) utilizando disolventes eutécticos profundos como absorbentes.es_CO
    dc.typehttp://purl.org/coar/resource_type/c_7a1fes_CO
    dc.date.accepted2020-06-22-
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