• Repositorio Institucional Universidad de Pamplona
  • Tesis de maestría y doctorado
  • Facultad de Ciencias Básicas
  • Maestría en Química
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    dc.contributor.authorMorinelly Villamizar, Cristhian Alberto.-
    dc.date.accessioned2025-05-15T15:34:57Z-
    dc.date.available2022-
    dc.date.available2025-05-15T15:34:57Z-
    dc.date.issued2022-
    dc.identifier.citationMorinelly Villamizar, C. A. (2022). Evaluación de las Interacciones Tiofeno e Hidrocarburos para el entendimiento de la afinidad de líquidos Iónicos (LI) de Imidazolio a partir de volúmenes de exceso Molar y variaciones del índice de refracción de mezclas binarias [Trabajo de Grado Maestría, Universidad de Pamplona]. Repositorio Hulago Universidad de Pamplona. http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/9504es_CO
    dc.identifier.urihttp://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/9504-
    dc.descriptionSe determinaron densidades e índices de refracción de mezclas binarias de 1 -Etil-3- metilimidazolio metanosulfonato, 1 -Etil-3-metilimidazolio tiocianato, 1 -Etil-3-metilimidazolio Etil Sulfato, hexano, ciclohexano, benceno, heptano, nonano, dodecano con tiofeno y a partir de estos datos se calcularon propiedades de exceso como volumen de exceso molar y variación del índice de refracción a 298,15 y 308,15K. El volumen de exceso molar y la desviación del índice de refracción para estos sistemas se ajustaron a una ecuación polinomial de Redlich-Kister. Las densidades de las mezclas binarias con los hidrocarburos obtenidas mostraron que en fracciones ricas en hidrocarburos estas aumentan con el número de átomos de carbono, Las densidades de las mezclas disminuyeron con el aumento de la temperatura. Los volúmenes de exceso molar fueron positivos en todo el rango de fracción molar en los solventes estudiados y aumentaron levemente con la temperatura, las variaciones en el índice de refracción tendieron hacia valores negativos en la mayoría de los casos. Los cambios de índice de refracción produjeron valores negativos en todo el rango de fracción molar para las seis mezclas con hidrocarburos investigadas; el valor menos negativo se reporta para la mezcla benceno + tiofeno, el valor más negativo del cambio de índice de refracción es para la mezcla dodecano + tiofeno. Para las mezclas binarias estudiadas los factores que influyen en el valor y el signo del cambio de índice de refracción y volumen de exceso molar son entre otras la diferencia en la forma, el tamaño y polaridad de las moléculas y la variación de las fuerzas existentes entre las moléculas de los compuestos puros con la adición de un nuevo componentees_CO
    dc.description.abstractDensities and refractive indices of binary mixtures of 1 -Ethyl-3-methylimidazolium methanesulfonate, 1 -Ethyl-3-methylimidazolium thiocyanate, 1 -Ethyl-3-methylimidazolium Ethyl Sulfate, hexane, cyclohexane, benzene, heptane, nonane, dodecane with thiophene and from these data excess properties are calculated as molar excess volume and refractive index change at 298,15 and 308,15K. The molar excess volume and refractive index deviation for these systems were fitted to a Redlich-Kister polynomial equation. The densities of the binary mixtures with the hydrocarbons obtained showed that in fractions rich in these hydrocarbons they increase with the number of carbon atoms. The densities of the mixtures decreased with increasing temperature. The volumes of molar excess were positive throughout the range of molar fraction in the studied solvents and increased slightly with temperature, the variations in the refractive index tended towards negative values in most cases. The refractive index changes produce negative values throughout the molar fraction range for the six mixtures with hydrocarbons investigated; the least negative value is reported for the benzene + thiophene mixture, the most negative value of the refractive index change is for the dodecane + thiophene mixture. For the binary mixtures studied, the factors that influence the value and sign of the change in refractive index and molar excess volume are, among others, the difference in the shape, size and polarity of the molecules and the variation of the forces existing between them, the molecules of pure compounds with the addition of a new component.es_CO
    dc.format.extent60es_CO
    dc.format.mimetypeapplication/pdfes_CO
    dc.language.isoeses_CO
    dc.publisherUniversidad de Pamplona – Facultad de Ciencias Básicas.es_CO
    dc.subjectLíquidos iónicos.es_CO
    dc.subjectVolumen de exceso molar.es_CO
    dc.subjectCambio de índice de refracción.es_CO
    dc.subjectEcuación polinomial de Redlich-Kister.es_CO
    dc.subjectFuerzas intermoleculares.es_CO
    dc.titleEvaluación de las Interacciones Tiofeno e Hidrocarburos para el entendimiento de la afinidad de líquidos Iónicos (LI) de Imidazolio a partir de volúmenes de exceso Molar y variaciones del índice de refracción de mezclas binarias.es_CO
    dc.typehttp://purl.org/coar/resource_type/c_bdcces_CO
    dc.date.accepted2022-
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    Aparece en las colecciones: Maestría en Química

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