• Repositorio Institucional Universidad de Pamplona
  • Trabajos de pregrado y especialización
  • Facultad de Ciencias Básicas
  • Química
  • Please use this identifier to cite or link to this item: http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/3515
    Full metadata record
    DC FieldValueLanguage
    dc.contributor.authorReyes Fernández, Leonardo Steyman.-
    dc.date.accessioned2022-10-04T16:30:24Z-
    dc.date.available2022-03-10-
    dc.date.available2022-10-04T16:30:24Z-
    dc.date.issued2022-
    dc.identifier.citationReyes Fernández, L. S. (2021). Evaluación de los coeficientes de actividad en mezclas binarias de THF/solvente orgánico en el equilibrio liquido-vapor (ELV) a partir de minería de datos mediante modelos empíricos, distribución local y contribución de grupos [Trabajo de Grado Pregrado, Universidad de Pamplona. http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/3515es_CO
    dc.identifier.urihttp://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/3515-
    dc.descriptionEl tetrahidrofurano (THF) es un solvente aprótico con múltiples aplicaciones en diversas áreas de las industrias química, petroquímica y farmacéutica con un impacto importante en la industria química. residuos líquidos con otros disolventes. En este trabajo, 51 datos VLE disponibles, para mezclas binarias isotérmicas de THF (1) + benceno (2) y THF (1) + ciclohexano (2) a 303,15 y 333,15 K, respectivamente, y THF isobárico (1) + metanol (2) a 103 kPa y THF (1) + etanol (2) a 100 kPa se utilizaron en el desarrollo de los modelos de coeficientes de actividad. La calidad de los datos experimentales se verificó mediante la prueba de Herington, el Test infinito de Kojima y el Test directo de Van Nes. Los datos binarios de VLE se correlacionaron con los modelos: Margules, Van laar, Wilson, NRTL, UNIQUAC, y UNIFAC para obtener parámetros binarios y coeficientes de actividades_CO
    dc.description.abstractEl autor no proporciona la información sobre este ítem.es_CO
    dc.format.extent123es_CO
    dc.format.mimetypeapplication/pdfes_CO
    dc.language.isoeses_CO
    dc.publisherUniversidad de Pamplona – Facultad de Ciencias Basicas.es_CO
    dc.subjectEquilibrio líquido de vapor (ELV).es_CO
    dc.subjectTHF.es_CO
    dc.subjectBenceno.es_CO
    dc.subjectCiclohexano.es_CO
    dc.subjectMetanol.es_CO
    dc.subjectEtanol RMSD.es_CO
    dc.subjectConsistencia Termodinámica.es_CO
    dc.titleEvaluación de los coeficientes de actividad en mezclas binarias de THF/solvente orgánico en el equilibrio liquido-vapor (ELV) a partir de minería de datos mediante modelos empíricos, distribución local y contribución de grupos.es_CO
    dc.typehttp://purl.org/coar/resource_type/c_7a1fes_CO
    dc.date.accepted2021-12-10-
    dc.relation.referencesTetrahydrofuran “THF/Tetrahydrofuran” | Products | Mitsubishi Chemical Corporation https://www.mchemical.co.jp/en/products/departments/mcc/c4/product/1201006_7922.html (accessed May 9, 2021).es_CO
    dc.relation.referencesSamsonova, T. I.; Mikhailov, G. D.; Bagrov, B. M.; Chegolya, A. S. Polymerization of Tetrahydrofuran in the Presence of Acetic Anhydride and Perchloric Acid. Fibre Chem. 1984, 15 (5), 349–353. https://doi.org/10.1007/BF00548131.es_CO
    dc.relation.referencesTetrahydrofuran - High Purity Solvents | Sigma-Aldrich https://www.sigmaaldrich.com/chemistry/solvents/tetrahydrofuran-center.html (accessed May 9, 2021).es_CO
    dc.relation.referencesParveen, S.; Singh, S.; Shukla, D.; Singh, K. P.; Gupta, M.; Shukla, J. P. Molecular Interaction Study of Binary Mixtures of THF with Methanol and O-Cresol - An Optical and Ultrasonic Study. Acta Phys. Pol. A 2009, 116 (6), 1011–1017. https://doi.org/10.12693/APhysPolA.116.1011.es_CO
    dc.relation.referencesNain, A. K. Densities and Volumetric Properties of Binary Mixtures of Tetrahydrofuran with Some Aromatic Hydrocarbons at Temperatures from 278.15 to 318.15 K. J. Solution Chem. 2006, 35 (10), 1417–1439. https://doi.org/10.1007/s10953-006-9071-8.es_CO
    dc.relation.referencesTilstam, U. Sulfolane.. A Versatile Dipolar Aprotic Solvent. Tilstam, U. Org. Process Res. Dev. 2012..Pdf. Org. Process Res. Dev. 2012, No. 16, 1273–1278.es_CO
    dc.relation.referencesZhang, Z.; Yang, L.; Xing, Y.; Li, W. Vapor-Liquid Equilibrium for Ternary and Binary Mixtures of 2-Isopropoxypropane, 2-Propanol, and N, N-Dimethylacetamide at 101.3 KPa. J. Chem. Eng. Data 2013, 58 (2), 357–363. https://doi.org/10.1021/je300994yes_CO
    dc.relation.referencesIsikgor, F. H.; Becer, C. R. Lignocellulosic Biomass: A Sustainable Platform for the Production of Bio-Based Chemicals and Polymers. Polym. Chem. 2015, 6es_CO
    dc.relation.references4497–4559. https://doi.org/10.1039/c5py00263j.es_CO
    dc.relation.referencesNo, C. a S. Toxicological Review Of. Rev. Lit. Arts Am. 2010, 39 (110), 759– 786. https://doi.org/http://www.epa.gov/iris/toxreviews/0070tr.pdf.es_CO
    dc.relation.referencesFowles, J.; Boatman, R.; Bootman, J.; Lewis, C.; Morgott, D.; Rushton, E.; Van Rooij, J.; Banton, M. A Review of the Toxicological and Environmental Hazards and Risks of Tetrahydrofuran. Crit. Rev. Toxicol. 2013, 43 (10), 811–828. https://doi.org/10.3109/10408444.2013.836155.es_CO
    dc.relation.referencesWood, L. Global Tetrahydrofuran (THF) Market Report 2020-2025: Growing Demand for Polytetramethylene Ether Glycol (PTMEG) https://www.prnewswire.com/news-releases/global-tetrahydrofuran-thf-marketreport-2020-2025-growing-demand-for-polytetramethylene-ether-glycol-ptmeg301188696.html (accessed May 12, 2021).es_CO
    dc.relation.referencesTetrahydrofuran (THF) - Market Study by Global Industry Analysts, Inc. https://www.strategyr.com/market-report-tetrahydrofuran-thf-forecasts-globalindustry-analysts-inc.asp (accessed May 19, 2021).es_CO
    dc.relation.referencesGlobal Tetrahydrofuran (THF) Market i https://teachin.id/blogs/3589/GlobalTetrahydrofuran-THF-Market-i (accessed May 19, 2021).es_CO
    dc.relation.referencesGlobal Tetrahydrofuran Market Size, Share | Industry Report 2027 https://marketresearch.biz/report/tetrahydrofuran-market/ (accessed May 19, 2021).es_CO
    dc.relation.referencesGómez, A. Simulación Del Proceso de Deshidratación Del Tetrahidrofurano Por Medio De Destilación Extractiva Utilizando Aspen Plus. 2007, 107.es_CO
    dc.relation.referencesSmith, J. M.; Van Ness, H. C.; Abbott, M. Introduction to Chemical Engineering Thermodynamics; CHEMICAL ENGINEERING SERIES; McGraw-Hill Education, 2005.es_CO
    dc.relation.referencesFranco, J. P. Determinación Experimental Del Equilibrio Entre Fases de Sistemas Azeotrópicos Relacionados Con Biocombustibles. Selección de Entrainers de Bajo Impacto Ambiental. 2016.es_CO
    dc.relation.referencesTosun, I. Vapor-Liquid Equilibrium. In The Thermodynamics of Phase and Reaction Equilibria; Elsevier, 2013; pp 351–446. https://doi.org/10.1016/b978-0-44459497-6.00009-8.es_CO
    dc.relation.referencesNguyen, T. K. Chemical Engineering Thermodynamics II (CHE 303 Course Notes) Chemical and Materials Engineering Cal Poly Pomona. 2009, No. Winteres_CO
    dc.relation.referencesRoizard, D.; Lorraine, C.-U. De. Encyclopedia of Membranes. Encycl. Membr. 2020, No. 2, 4–6. https://doi.org/10.1007/978-3-642-40872-4.es_CO
    dc.relation.referencesSu, W.; Zhao, L.; Deng, S. Recent Advances in Modeling the Vapor-Liquid Equilibrium of Mixed Working Fluids. Fluid Phase Equilib. 2017, 432, 28–44. https://doi.org/10.1016/j.fluid.2016.10.016.es_CO
    dc.relation.referencesKoretsky, M. D. Engineering and Chemical Thermodynamics; Wiley, 2012es_CO
    dc.relation.referencesBall, D. W. Physical Chemistry; Cengage Learning, 2014.es_CO
    dc.relation.referencesEindhoven, T. U.; Version, D. Combinatorial and Dispersion Activity Coefficient Models for Combinatorial and Dispersion Activity Coefficient Models; 2021.es_CO
    dc.relation.referencesDEPARTMENT OF CHEMICAL ENGINEERING UNIT – I - Properties of Solutions – SCHA1302es_CO
    dc.relation.referencesWilson, L.; Wilson, H. Preface to the Memorial Edition for Grant M. Wilson. J. Chem. Eng. Data 2014, 59 (4), 943–945. https://doi.org/10.1021/je500128s.es_CO
    dc.relation.referencesRenon, H.; Prausnitz, J. M. Estimation of Parameters for the Nrtl Equation for Excess Gibbs Energies of Strongly Nonideal Liquid Mixtures. Ind. Eng. Chem. Process Des. Dev. 1969, 8 (3), 413–419. https://doi.org/10.1021/i260031a019.es_CO
    dc.relation.referencesMuzenda, E. From UNIQUAC to Modified UNIFAC Dortmund : A Discussion. 3rd Int. Conf. Med. Sci. Chem. Eng. 2013, No. 5, 32–41.es_CO
    dc.relation.referencesBehera, M. Vapor Liquid Equilibrium Modeling Using UNIFAC Group Contribution Method and Its Application In Distillation Column Design and Steady State Simulation. Thesis - Bachelor 2010.es_CO
    dc.relation.referencesManufacture Process Of Tetrahydrofuran - EME - News - Henan EME Technology Co.,Ltd http://www.chinafuran.com/news/manufacture-process-oftetrahydrofuran-14568925.html (accessed May 15, 2021).es_CO
    dc.relation.referencesParod, R. J. Tetrahydrofuran. Encycl. Toxicol. Third Ed. 2014, 4, 505–508. https://doi.org/10.1016/B978-0-12-386454-3.00437-1.es_CO
    dc.relation.referencesTetrahydrofuran - American Chemical Society https://www.acs.org/content/acs/en/molecule-of-theweek/archive/t/tetrahydrofuran.html (accessed May 15, 2021).es_CO
    dc.relation.referencesChen, S.; Wojcieszak, R.; Dumeignil, F.; Marceau, E.; Royer, S. How Catalysts and Experimental Conditions Determine the Selective Hydroconversion of Furfural and 5-Hydroxymethylfurfural. Chem. Rev. 2018, 118 (22), 11023–11117. https://doi.org/10.1021/acs.chemrev.8b00134.es_CO
    dc.relation.referencesDedecker, K.; Dumas, E.; Lavédrine, B.; Steunou, N.; Serre, C. 5 - MetalOrganic Frameworks for the Capture of Volatile Organic Compounds and Toxic Chemicals; 2019. https://doi.org/10.1016/B978-0-12-814633-0.00007-7. (35) Albers, P. W.; Lennon, D.; Parker, S. F. Catalysis; 2017; Vol. 49.es_CO
    dc.relation.referencesAlbers, P. W.; Lennon, D.; Parker, S. F. Catalysis; 2017; Vol. 49. https://doi.org/10.1016/B978-0-12-805324-9.00005-4.es_CO
    dc.relation.referencesVulimiri, S. V.; Margaret Pratt, M.; Kulkarni, S.; Beedanagari, S.; Mahadevan, B. Reproductive and Developmental Toxicity of Solvents and Gases; Elsevier Inc., 2017. https://doi.org/10.1016/B978-0-12-804239-7.00021-4.es_CO
    dc.relation.referencesAbel, E. L.; DiGiovanni, J. Environmental Carcinogenesis. Mol. Basis Cancer 2008, 91–113. https://doi.org/10.1016/B978-141603703-3.10007-X.es_CO
    dc.relation.referencesCyclohexane | National Pollutant Inventory http://www.npi.gov.au/resource/cyclohexane (accessed Oct 18, 2021).es_CO
    dc.relation.referencesTang, K.; Bai, P.; Huang, C.; Liu, W. Separation of Tetrahydrofuran-Ethanol Azeotropic Mixture by Extractive Distillation. Asian J. Chem. 2013, 25 (5), 2774– 2778. https://doi.org/10.14233/ajchem.2013.13870.es_CO
    dc.relation.referencesVeritrade | Importaciones y Exportaciones de TETRAHIDROFURANO https://www.veritradecorp.com/es/colombia/importaciones-yexportaciones/tetrahidrofurano/293211 (accessed May 21, 2021).es_CO
    dc.relation.referencesD. Properties of Tetrahydrofuran. Sugar Ser. 2000, 13 (C), 242. https://doi.org/10.1016/S0167-7675(00)80037-8.es_CO
    dc.relation.referencesMorgunov, K. G. Thermodynamic Data Bank: The Principles, Organization, and Structure of Software. Russ. J. Phys. Chem. A 2010, 84 (5), 728–734. https://doi.org/10.1134/S0036024410050031.es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of 1,2-Ethanediol + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE 1,2Ethanediol%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Tetrahydrofuran + Water from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Tetrahydrofuran%3BWater.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Ethanol + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Ethanol%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Hexane + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Hexane%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Acetic acid + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Acetic acid%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Benzene + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Benzene%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Cyclohexane + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Cyclohexane%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Cyclohexane + Tetrahydrofuran from Dortmund Data Bank http://www.ddbst.com/en/EED/VLE/VLE Cyclohexane%3BTetrahydrofuran.php (accessed May 19, 2021).es_CO
    dc.relation.referencesScopus preview - Scopus - Welcome to Scopus https://www.scopus.com/standard/marketing.uri (accessed Nov 22, 2021).es_CO
    dc.relation.referencesLeal de Pérez, M. C.; Pérez Camacho, E. E.; Morán Guillén, H. A.; Barrera Petit, W. J.; Pérez Ones, O.; García López, A. Modelado Matemático Del Equilibrio Líquido Vapor de Mostos de <em>Agave Cocui</Em>. ACI Av. en Ciencias e Ing. 2015, 7 (2). https://doi.org/10.18272/aci.v7i2.266.es_CO
    dc.relation.referencesSarría, F. A.; Palazón, J. A. Modelos y Modelización. Model. Sist. Ambient. 2008, 43–52.es_CO
    dc.relation.referencesNon-Ideal Vapor-Liquid Equilibrium (VLE) Modeled by the Margules Equation - Wolfram Demonstrations Project https://demonstrations.wolfram.com/NonIdealVaporLiquidEquilibriumVLEModeledB yTheMargulesEquatio/ (accessed May 21, 2021).es_CO
    dc.relation.referencesKovalenko, N. A. The Generalized Local Composition Model: Its Features and Limitations. Russ. J. Phys. Chem. A 2019, 93 (10), 1918–1922. https://doi.org/10.1134/S0036024419100145es_CO
    dc.relation.referencesWilson, G.M. Vapor-Liquid Equilibrium. XI. A New Expression for the Excess Free Energy of Mixing. J. Am. Chem. Soc. 1964, 86, 127–130.es_CO
    dc.relation.referencesRenon, H.; Prausnitz, J.M. Local Compositions in Thermodynamic Excess Functions for Liquid Mixtures. AICHE J. 1968, 14, 135–144.es_CO
    dc.relation.referencesAbrams, D.S.; Prausnitz, J.M. Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems. AIChE J. 1975, 21, 116–128. [CrossRef]es_CO
    dc.relation.referencesPoling, B.E.; Prausnitz, J.M.; O’Connell, J.P. The Properties of Gases and Liquids, 5th ed.; McGrawHill: New York, NY, USA, 2001.es_CO
    dc.relation.referencesElvis Judith Hernández Ramos Tesis Doctoral. 2010.es_CO
    dc.relation.referencesJ.A.Nelder and R. Mead, “A simplex method for function minization”, Computer Journal 7 (1965): 308-313es_CO
    dc.relation.referencesHiaki, T.; Taniguchi, A.; Tsuji, T.; Hongo, M. Isothermal Vapor-Liquid Equilibria of Octane with 1-Butanol, 2-Butanol, or 2-Methyl-2-Propanol. Fluid Phase Equilib. 1998, 144 (1–2), 145–155. https://doi.org/10.1016/s0378-3812(97)00253-7.es_CO
    dc.relation.referencesJackson, P.; Wilsak, R. Thermodynamic consistency tests based on the GibbsDuhem equation applied to isothermal, binary vapor-liquid equilibrium data: Data evaluation and model testing. Fluid Phase Equilibria 1995, 103, 155–197.es_CO
    dc.relation.referencesHerington, E.F. Test for the Consistency of Experimental Isobaric Vapor-liquid Equilibrium Data. J. Znst. Pet. 1961, 37, 457–470.es_CO
    dc.relation.referencesAvailable online: https://trc.nist.gov/TDE/Help/TDE103b/ExptAndPredictedData-Binary.htm (accessed on 16 September 2021).es_CO
    dc.relation.referencesJelić, J. M.; Tasić, A. Ž.; Djordjević, B. D.; Šerbanović, S. P. Use of the SSF Equations in the Kojima-Moon-Ochi Thermodynamic Consistency Test of Isothermal Vapour-Liquid Equilibrium Data. J. Serbian Chem. Soc. 2000, 65 (12), 877–889. https://doi.org/10.2298/jsc0012877jes_CO
    dc.relation.referencesleast squares method | Definition & Explanation | Britannica https://www.britannica.com/topic/least-squares-approximation (accessed Nov 27, 2021).es_CO
    dc.relation.references(Book) Testing of vapor-liquid equilibrium data for thermodynamic consistency by Richard Patrick Frutiger Download PDF EPUB FB2 https://sedelekugih.trc-music.com/testing-of-vapor-liquid-equilibrium-data-forthermodynamic-consistency-book-17176pf.php (accessed Nov 22, 2021).es_CO
    dc.relation.referencesDahm, K.; Visco, D. Fundamentals of Chemical Engineering Thermodynamics; 2014.es_CO
    dc.relation.referencesVapor-Liquid Equilibrium Data of Benzene + Tetrahydrofuran from Dortmund Data Bank. Available online: http://www.ddbst. com/en/EED/VLE/VLE%20Benzene%3BTetrahydrofuran.phpes_CO
    dc.relation.referencesBinary Vapor-Liquid Equil. Data. Available online: https://www.cheric.org/research/kdb/hcvle/showvle.php?vleid=3848es_CO
    dc.relation.referencesLi, Q.; Liu, P.; Cao, L.; Wen, F.; Zhang, S.; Wang, B. Vapor-Liquid Equilibrium for Tetrahydrofuran+methanol+tetrafluoroborateBased Ionic Liquids at 101.3kPa. Fluid Phase Equilibria 2013, 360, 439–444.es_CO
    dc.relation.referencesBinary Vapor-Liquid Equil. Available online: https://www.cheric.org/research/kdb/hcvle/showvle.php?vleid=2376es_CO
    dc.relation.referencesACD/ChemSketch, version 2021.1.3, Advanced Chemistry Development, Inc., Toronto, ON, Canada, www.acdlabs.com, 2021.es_CO
    dc.relation.referencesVapor Pressure Calculation by Antoine Equation (Tetrahydrofuran) http://ddbonline.ddbst.com/antoinecalculation/antoinecalculationcgi.exe (accessed Nov 27, 2021es_CO
    dc.relation.referencesVapor Pressure Calculation by Antoine Equation (Benzene) http://ddbonline.ddbst.com/antoinecalculation/antoinecalculationcgi.exe (accessed Nov 27, 2021).es_CO
    dc.relation.referencesVapor Pressure Calculation by Antoine Equation (Methanol) http://ddbonline.ddbst.com/antoinecalculation/antoinecalculationcgi.exe (accessed Nov 27, 2021).es_CO
    dc.relation.referencesVapor Pressure Calculation by Antoine Equation (Benzene) http://ddbonline.ddbst.com/antoinecalculation/antoinecalculationcgi.exe (accessed Nov 27, 2021).es_CO
    dc.relation.referencesVapor Pressure Calculation by Antoine Equation (Ethanol) http://ddbonline.ddbst.com/antoinecalculation/antoinecalculationcgi.exe (accessed Nov 27, 2021).es_CO
    dc.relation.referencesFernández, L. S. R.; Amado-Gonzaléz, E.; Hurtado, E. G. Y. Study of Thermodynamic Modeling of Isothermal and Isobaric Binary Mixtures in VaporLiquid Equilibrium (VLE) of Tetrahydrofuran with Benzene (303.15 K) Cyclohexane (333.15 K), Methanol (103 KPa), and Ethanol (100 KPa). Thermo 2021, 1 (3), 286– 296. https://doi.org/10.3390/thermo1030019.es_CO
    dc.rights.accessrightshttp://purl.org/coar/access_right/c_abf2es_CO
    dc.type.coarversionhttp://purl.org/coar/resource_type/c_2df8fbb1es_CO
    Appears in Collections:Química

    Files in This Item:
    File Description SizeFormat 
    Reyes_2021_TG.pdfReyes_2021_TG5,01 MBAdobe PDFView/Open


    Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.