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    dc.contributor.authorGomez Jaramillo, Wilfred Andres.-
    dc.date.accessioned2022-06-23T23:51:33Z-
    dc.date.available2017-03-13-
    dc.date.available2022-06-23T23:51:33Z-
    dc.date.issued2017-
    dc.identifier.citationGomez Jaramillo, W. A. (2016). Equilibrio de fases en mezclas asimétricas de interés para la industria de Petróleo a partir de ecuaciones de estado incluyendo efectos asociativos [Trabajo de Grado Pregrado, Universidad de Pamplona]. Repositorio Hulago Universidad de Pamplona. http://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/2310es_CO
    dc.identifier.urihttp://repositoriodspace.unipamplona.edu.co/jspui/handle/20.500.12744/2310-
    dc.descriptionLa Ingeniería del Equilibrio de Fases comprende la utilización del conocimiento termodinámico del comportamiento de fases en distintos tipos de mezclas, y su cuantificación por medio de modelos matemáticos, para contribuir al desarrollo de procesos, ya sean estos químicos (con reacción), de separación, extracción, etc. En especial, la aplicación de la termodinámica asume un rol fundamental en el desarrollo de procesos donde están presentes los fluidos supercríticos debido a los múltiples y grado de complejidad de los tipos de comportamiento de fases que se observan en las mezclas con fluidos supercríticos a altas presiones, los que según el caso pueden resultar provechosos o limitantes para un problema tecnológico dado. En este contexto resulta fundamental para la explotación de hidrocarburos contar con herramientas de cálculo que permitan distinguir en las regiones en una fase en función de presión y temperatura, de inmiscibilidad y de miscibilidad de acuerdo a una ecuación de estado (EoS) para obtener una descripción cuantitativa de las composiciones de las fases en equilibrio en amplios rangos de condiciones. Por lo tanto, en el presente trabajo se desarrolló un algoritmo capaz de predecir el equilibrio de fases en mezclas asimétricas de interés para la industria del petróleo a partir de ecuaciones de estado incluyendo efectos asociativos, donde se emplearon las ecuaciones de estado Pen-Robinson y RKPR para las mezclas asimétricas de CO2 + ( fenantreno, antraceno, pireno, criseno, trifenileno , n-tetracosano, noctacosano, n-dotricontano) y analizó la importancia que de un tercer parámetro en la estructura de una ecuación de estado, como también la necesidad de implementar parámetros de interacción binaria. Se obtuvieron desviaciones en fracción molar de precipitación de los sólidos diferentes a CO2, para la serie CO2 + fenantreno, antraceno, pireno entre el 5% y 19% y para CO2 + criseno, trifenileno entre el 2% y 9%. La serie de CO2 + ntetracosano, n-octacosano, n-dotricontano arrojo desviaciones entre el 5% y 7 % en fracción molar del precipitado, en general para los dos modelos de ecuaciones de estados implementados en este trabajo.es_CO
    dc.description.abstractPhase Equilibrium Engineering involves the use of thermodynamic knowledge of phase behavior in different types of mixtures, and its quantification through mathematical models, to contribute to the development of processes, whether these chemical (with reaction), separation, Extraction, etc. In particular, the application of thermodynamics assumes a fundamental role in the development of processes where the supercritical fluids are present due to the multiple and the degree of complexity of the types of phase behavior that are observed in the mixtures with supercritical fluids at high pressures, Which depending on the case may prove beneficial or limiting for a given technological problem. In this context, it is essential for the hydrocarbon exploitation to have calculation tools that allow to distinguish in the regions in a phase as a function of pressure and temperature, immiscibility and miscibility according to a state equation (EoS) to obtain the description Quantitative composition of equilibrium phases over wide ranges of conditions. Therefore, an algorithm capable of predicting phase equilibria in asymmetric mixtures of interest to the petroleum industry was developed from state equations including associative effects, where the Pen-Robinson equations of state were used. RKPR for asymmetric CO2 + mixtures (phenanthrene, anthracene, pyrene, chrysene, triphenylene, n-tetracosan, n-octacosane, n-dotricontane) and analyzed the importance of a third parameter in the structure of an state of equation as well as the need To implement binary interaction parameters. Deviations were obtained in the molar fraction of precipitation of the solids other than CO2, for the CO 2 + phenanthrene, anthracene, pyrene series between 5% and 19% and for CO2 + chrysene, triphenylene between 2% and 9%. The series of CO 2 + ntetracosan, n-octacosane, n-dotricontane yielded deviations between 5% and 7% in molar fraction of the precipitate, in general for the two models of state equations implemented in this work.es_CO
    dc.format.extent62es_CO
    dc.format.mimetypeapplication/pdfes_CO
    dc.publisherUniversidad de Pamplona – Facultad de Ingenierías y Arquitectura.es_CO
    dc.subjectEl autor no proporciona la información sobre este ítem.es_CO
    dc.titleEquilibrio de fases en mezclas asimétricas de interés para la industria de Petróleo a partir de ecuaciones de estado incluyendo efectos asociativos.es_CO
    dc.typehttp://purl.org/coar/resource_type/c_7a1fes_CO
    dc.date.accepted2016-12-13-
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    dc.type.coarversionhttp://purl.org/coar/resource_type/c_2df8fbb1es_CO
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